Category: The Right Chemistry

A normal, everyday Monday morning at Energy Geek Central. Yes, this is a normal conversation for me to take part in on a Monday morning. Energy geekery at breakfast. Perfect.

Nuclear Flower Power

This whole UK Government nuclear power programme plan is ridiculous ! 75 gigawatts (GW) of Generation III nuclear fission reactors ? What are they thinking ? Britain would need to rapidly ramp up its construction capabilities, and that’s not going to happen, even with the help of the Chinese. (And the Americans are not going to take too kindly to the idea of China getting strongly involved with British energy). And then, we’d need to secure almost a quarter of the world’s remaining reserves of uranium, which hasn’t actually been dug up yet. And to cap it all, we’d need to have 10 more geological disposal repositories for the resulting radioactive spent fuel, and we haven’t even managed to negotiate one yet. That is, unless we can burn a good part of that spent fuel in Generation IV nuclear fission reactors – which haven’t even been properly demonstrated yet ! Talk about unconscionable risk !

Baseload Should Be History By Now, But…

Whatever the technological capability for nuclear power plants to “load follow” and reduce their output in response to a chance in electricity demand, Generation III reactors would not be run as anything except “baseload” – constantly on, and constantly producing a constant amount of power – although they might turn them off in summer for maintenance. You see, the cost of a Generation III reactor and generation kit is in the initial build – so their investors are not going to permit them to run them at low load factors – even if they could.

There are risks to running a nuclear power plant at partial load – mostly to do with potential damage to the actual electricity generation equipment. But what are the technology risks that Hinkley Point C gets built, and all that capital is committed, and then it only runs for a couple of years until all that high burn up fuel crumbles and the reactors start leaking plutonium and they have to shut it down permanently ? Who can guarantee it’s a sound bet ?

If they actually work, running Generation III reactors at constant output as “baseload” will also completely mess with the power market. In all of the scenarios, high nuclear, high non-nuclear, or high fossil fuels with Carbon Capture and Storage (CCS), there will always need to be some renewables in the mix. In all probability this will be rapidly deployed, highly technologically advanced solar power photovoltaics (PV). The amount of solar power that will be generated will be high in summer, but since you have a significant change in energy demand between summer and winter, you’re going to have a massive excess of electricity generation in summer if you add nuclear baseload to solar. Relative to the demand for energy, you’re going to get more Renewable Energy excess in summer and under-supply in winter (even though you get more offshore wind in winter), so it’s critical how you mix those two into your scenario.

The UK Government’s maximum 75 GW nuclear scenario comprises 55 GW Generation III and 20 GW Generation IV. They could have said 40 GW Gen III to feed Gen IV – the spent fuel from Gen III is needed to kick off Gen IV. Although, if LFTR took off, if they had enough fluoride materials there could be a Thorium way into Gen IV… but this is all so technical, no MP [ Member of Parliament ] is going to get their head round this before 2050.

The UK Government are saying that 16 GW of nuclear by 2030 should be seen as a first tranche, and that it could double or triple by 2040 – that’s one heck of a deployment rate ! If they think they can get 16 GW by 2030 – then triple that by 10 years later ? It’s not going to happen. And even 30 GW would be horrific. But it’s probably more plausible – if they can get 16 GW by 2030, they can arguably get double that by 2040.

As a rule of thumb, you would need around 10 tonnes of fissionable fuel to kickstart a Gen IV reactor. They’ve got 106 tonnes of Plutonium, plus 3 or 4 tonnes they recently acquired – from France or Germany (I forget which). So they could start 11 GW of Gen IV – possibly the PRISM – the Hitachi thing – sodium-cooled. They’ve been trying them since the Year Dot – these Fast Reactors – the Breeders – Dounreay. People are expressing more confidence in them now – “Pandora’s Promise” hangs around the narrative that the Clinton administration stopped research into Fast Reactors – Oak Ridge couldn’t be commercial. Throwing sodium around a core 80 times hotter than current core heats – you can’t throw water at it easily. You need something that can carry more heat out. It’s a high technological risk. But then get some French notable nuclear person saying Gen IV technologies – “they’re on the way and they can be done”.

Radioactive Waste Disposal Woes

The point being is – if you’re commissioning 30 GW of Gen III in the belief that Gen IV will be developed – then you are setting yourself up to be a hostage to technological fortune. That is a real ethical consideration. Because if you can’t burn the waste fuel from Gen III, you’re left with up to 10 radioactive waste repositories required when you can’t even get one at the moment. The default position is that radioactive spent nuclear fuel will be left at the power stations where they’re created. Typically, nuclear power plants are built on the coast as they need a lot of cooling water. If you are going for 30 GW you will need a load of new sites – possibly somewhere round the South East of England. This is where climate change comes in – rising sea levels, increased storm surge, dissolving, sinking, washed-away beaches, more extreme storms […] The default spent fuel scenario with numerous coastal decommissioned sites with radioactive interim stores which contain nearly half the current legacy radioactive waste […]

Based on the figures from the new Greenpeace report, I calculate that the added radioactive waste and radioactive spent fuel arisings from a programme of 16 GW of nuclear new build would be 244 million Terabequerel (TBq), compared to the legacy level of 87 million TBq.

The Nuclear Decommissioning Authority (NDA) are due to publish their Radioactive Waste Inventory and their Report on Radioactive Materials not in the Waste Inventory at the end of January 2014. We need to keep a watch out for that, because they may have adapted their anticipated Minimum and Maxmium Derived Inventory.

Politics Is Living In The Past

What you hear from politicians is they’re still talking about “baseload”, as if they’ve just found the Holy Grail of Energy Policy. And failed nuclear power. Then tidal. And barrages. This is all in the past. Stuff they’ve either read – in an article in a magazine at the dentist’s surgery waiting room, and they think, alright I’ll use that in a TV programme I’ve been invited to speak on, like Question Time. I think that perhaps, to change the direction of the argument, we might need to rubbish their contribution. A technological society needs to be talking about gasification, catalysis. If you regard yourselves as educated, and have a technological society – your way of living in the future is not only in manufacturing but also ideas – you need to be talking about this not that : low carbon gas fuels, not nuclear power. Ministers and senior civil servants probably suffer from poor briefing – or no briefing. They are relying on what is literally hearsay – informal discussions, or journalists effectively representing industrial interests. Newspapers are full of rubbish and it circulates, like gyres in the oceans. Just circulates around and around – full of rubbish.

I think part of the problem is that the politicians and chief civil servants and ministers are briefed by the “Old Guard” – very often the ex-nuclear power industry guard. They still believe in big construction projects, with long lead times and massive capital investment, whereas Renewable Electricity is racing ahead, piecemeal, and private investors are desperate to get their money into wind power and solar power because the returns are almost immediate and risk-free.

Together in Electric Dreams

Question : Why are the UK Government ploughing on with plans for so much nuclear power ?

1. They believe that a lot of transport and heat can be made to go electric.
2. They think they can use spent nuclear fuel in new reactors.
3. They think it will be cheaper than everything else.
4. They say it’s vital for UK Energy Security – for emissions reductions, for cost, and for baseload. The big three – always the stated aim of energy policy, and they think nuclear ticks all those three boxes. But it doesn’t.

What they’ll say is, yes, you have to import uranium, but you’ve got a 4 year stock. Any war you’re going to get yourselves involved in you can probably resolve in 4 days, or 4 weeks. If you go for a very high nuclear scenario, you would be taking quite a big share of the global resource of uranium. There’s 2,600 TWh of nuclear being produced globally. And global final energy demand is around 100,000 TWh – so nuclear power currently produces around 2.6% of global energy supply. At current rates of nuclear generation, according to the World Nuclear Association, you’ve got around 80 years of proven reserves and probably a bit more. Let’s say you double nuclear output by 2050 or 2040 – but in the same time you might just have enough uranium – and then find a bit more. But global energy demand rises significantly as well – so nuclear will still only provide around 3% of global energy demand. That’s not a climate solution – it’s just an energy distraction. All this guff about fusion. Well.

Cornering The Market In Undug Uranium

A 75 GW programme would produce at baseload 590 TWh a year – divide by 2,600 – is about 23% of proven global uranium reserves. You’re having to import, regardless of what other countries are doing, you’re trying to corner the market – roughly a quarter. Not even a quarter of the market – a quarter of all known reserves – it’s not all been produced yet. It’s still in the ground. So could you be sure that you could actually run these power stations if you build them ? Without global domination of the New British Empire […]. The security issues alone – defending coastal targets from a tweeb with a desire to blow them up. 50 years down the line they’re full of radioactive spent fuel that won’t have a repository to go to – we don’t want one here – and how much is it going to cost ?

My view is that offshore wind will be a major contributor in a high or 100% Renewable Electricity scenario by 2050 or 2060. Maybe 180 GW, that will also be around 600 TWh a year – comparable to that maximum nuclear programme. DECC’s final energy demand 2050 – several scenarios – final energy demand from 6 scenarios came out as between roughly 1,500 TWh a year and the maximum 2,500 TWh. Broadly speaking, if you’re trying to do that just with Renewable Electricity, you begin to struggle quite honestly, unless you’re doing over 600 TWh of offshore wind, and even then you need a fair amount of heat pump stuff which I’m not sure will come through. The good news is that solar might – because of the cost and technology breakthroughs. That brings with it a problem – because you’re delivering a lot of that energy in summer. The other point – David MacKay would say – in his book his estimate was 150 TWh from solar by 2050, on the grounds that that’s where you south-facing roofs are – you need to use higher efficiency triple junction cells with more than 40% efficiency and this would be too expensive for a rollout which would double or triple that 150 TWh – that would be too costly – because those cells are too costly. But with this new stuff, you might get that. Not only the cost goes down, but the coverage goes down. Not doing solar across swathes of countryside. There have always been two issues with solar power – cost and where it’s being deployed.

Uh-Oh, Summer Days. Uh-Oh, Summer Nights

With the solar-wind headline, summer days and summer nights are an issue.

With the nuclear headline, 2040 – they would have up to 50 GW, and that would need to run at somewhere between 75% and 95% capacity – to protect the investment and electric generation turbines.

It will be interesting to provide some figures – this is how much over-capacity you’re likely to get with this amount of offshore wind. But if you have this amount of nuclear power, you’ll get this amount […]

Energy demand is strongly variable with season. We have to consider not just power, but heat – you need to get that energy out in winter – up to 4 times as much during peak in winter evenings. How are you going to do that ? You need gas – or you need extensive Combined Heat and Power (CHP) (which needs gas). Or you need an unimaginable deployment of domestic heat pumps. Air source heat pumps won’t work at the time you need them most. Ground source heat pumps would require the digging up of Britain – and you can’t do that in most urban settings.

District Heat Fields

The other way to get heat out to everyone in a low carbon world – apart from low carbon gas – is having a field-based ground source heat pump scheme – just dig up a field next to a city – and just put in pipes and boreholes in a field. You’re not disturbing anybody. You could even grow crops on it next season. Low cost and large scale – but would need a District Heating (DH) network. There are one or two heat pump schemes around the world. Not sure if they are used for cooling in summer or heat extraction in the winter. The other thing is hot water underground. Put in an extra pipe in the normal channels to domestic dwellings. Any excess heat from power generation or electrolysis or whatever is put down this loop and heats the sub-ground. Because heat travels about 1 metre a month in soil, that heat should be retained for winter. A ground source heat sink. Geothermal energy could come through – they’re doing a scheme in Manchester. If there’s a nearby heat district network – it makes it easier. Just want to tee it into the nearest DH system. The urban heat demand is 150 TWh a year. You might be able to put DH out to suburban areas as well. There are 9 million gas-connected suburban homes – another about 150 TWh there as well – or a bit more maybe. Might get to dispose of 300 TWh in heat through DH. The Green Deal insulation gains might not be what is claimed – and condensing gas boiler efficiencies are not that great – which feeds into the argument that in terms of energy efficiency, you not only want to do insulation, but also DH – or low carbon gas. Which is the most cost-effective ? Could argue reasonable energy efficiency measures are cheapest – but DH might be a better bet. That involves a lot of digging.

Gas Is The Logical Answer

But everything’s already laid for gas. (…but from the greatest efficiency first perspective, if you’re not doing DH, you’re not using a lot of Renewable Heat you could otherwise use […] )

The best package would be the use of low carbon gases and sufficient DH to use Renewable Heat where it is available – such as desalination, electrolysis or other energy plant. It depends where the electrolysis is being done.

The Age of Your Carbon

It also depends on which carbon atoms you’re using. If you are recycling carbon from the combustion of fossil fuels into Renewable Gas, that’s OK. But you can’t easily recapture carbon emissions from the built environment (although you could effectively do that with heat storage). You can’t do carbon capture from transport either. So your low carbon gas has to come from biogenic molecules. Your Renewable Gas has to be synthesised using biogenic carbon molecules rather than fossil ones.

[…] I’m using the phrase “Young Carbon”. Young Carbon doesn’t have to be from plants – biological things that grow.

Well, there’s Direct Air Capture (DAC). It’s simple. David Sevier, London-based, is working on this. He’s using heat to capture carbon dioxide. You could do it from exhaust in a chimney or a gasification process – or force a load of air through a space. He would use heat and cooling to create an updraft. It would enable the “beyond capture” problem to be circumvented. Cost is non-competitive. Can be done technically. Using reject heat from power stations for the energy to do it. People don’t realise you can use a lot of heat to capture carbon, not electricity.

Young Carbon from Seawater

If you’re playing around with large amounts of seawater anyway – that is, for desalination for irrigation, why not also do Renewable Hydrogen, and pluck the Carbon Dioxide out of there too to react with the Renewable Hydrogen to make Renewable Methane ? I’m talking about very large amounts of seawater. Not “Seawater Greenhouses” – condensation designs mainly for growing exotic food. If you want large amounts of desalinated water – and you’re using Concentrated Solar Power – for irrigating deserts – you would want to grow things like cacti for biological carbon.

Say you had 40 GW of wind power on Dogger Bank, spinning at 40% load factor a year. You’ve also got electrolysers there. Any time you’re not powering the grid, you’re making gas – so capturing carbon dioxide from seawater, splitting water for hydrogen, making methane gas. Wouldn’t you want to use flash desalination first to get cleaner water for electrolysis ? Straight seawater electrolysis is also being done.

It depends on the relative quantities of gas concentrated in the seawater. If you’ve got oxygen, hydrogen and carbon dioxide, that would be nice. You might get loads of oxygen and hydrogen, and only poor quantities of carbon dioxide ?

But if you could get hydrogen production going from spare wind power. And even if you had to pipe the carbon dioxide from conventional thermal power plants, you’re starting to look at a sea-based solution for gas production. Using seawater, though, chlorine is the problem […]

Look at the relative density of molecules – that sort of calculation that will show if this is going to fly. Carbon dioxide is a very fixed, stable molecule – it’s at about the bottom of the energy potential well – you have to get that reaction energy from somewhere.

How Much Spare Power Will There Be ?

If you’ve got an offshore wind and solar system. At night, obviously, the solar’s not working (unless new cells are built that can run on infrared night-time Earthshine). But you could still have 100 GWh of wind power at night not used for the power grid. The anticipated new nuclear 40 GW nuclear by 2030 will produce about 140 GWh – this would just complicate problems – adding baseload nuclear to a renewables-inclusive scenario. 40 GW is arguably a reasonable deployment of wind power by 2030 – low if anything.

You get less wind in a nuclear-inclusive scenario, but the upshot is you’ve definitely got a lot of power to deal with on a summer night with nuclear power. You do have with Renewable Electricity as well, but it varies more. Whichever route we take we’re likely to end up with excess electricity generation on summer nights.

In a 70 GW wind power deployment (50 GW offshore, 20 GW onshore – 160 TWh a year), you might have something like 50 to 100 GWh per night of excess (might get up to 150 GWh to store on a windy night). But if you have a 16 GW nuclear deployment by 2030 (125 TWh a year), you are definitely going to have 140 GWh of excess per night (that’s 16 GW for 10 hours less a bit). Night time by the way is roughly between 9pm and 7am between peak demands.

We could be making a lot of Renewable Gas !

Can you build enough Renewable Gas or whatever to soak up this excess nuclear or wind power ?

The energy mix is likely to be in reality somewhere in between these two extremes of high nuclear or high wind.

But if you develop a lot of solar – so that it knocks out nuclear power – it will be the summer day excess that’s most significant. And that’s what Germany is experiencing now.

Choices, choices, choices

There is a big choice in fossil fuels which isn’t really talked about very often – whether the oil and gas industry should go for unconventional fossil fuels, or attempt to make use of the remaining conventional resources that have a lower quality. The unconventionals narrative – shale gas, coalbed methane, methane hydrates, deepwater gas, Arctic oil and gas, heavy oil, is running out of steam as it becomes clear that some of these choices are expensive, and environmentally damaging (besides their climate change impact). So the option will be making use of gas with high acid gas composition. And the technological solutions for this will be the same as needed to start major production of Renewable Gas.

Capacity Payments

But you still need to answer the balancing question. If you have a high nuclear power scenario, you need maybe 50 TWh a year of gas-fired power generation. If high Renewable Electricity, you will need something like 100 TWh of gas, so you need Carbon Capture and Storage – or low carbon gas.

Even then, the gas power plants could be running only 30% of the year, and so you will need capacity payments to make sure new flexible plants get built and stay available for use.

If you have a high nuclear scenario, coupled with gas, you can meet the carbon budget – but it will squeeze out Renewable Electricity. If high in renewables, you need Carbon Capture and Storage (CCS) or Carbon Capture and Recycling into Renewable Gas, but this would rule out nuclear power. It depends which sector joins up with which.

Carbon Capture, Carbon Budget

Can the Drax power plant – with maybe one pipeline 24 inches in diameter, carrying away 20 megatonnes of carbon dioxide per year – can it meet the UK’s Carbon Budget target ?